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An In Situ Electrochemical Quartz Crystal Microbalance Study of the Dissolution Process of a Gold Electrode in Perchloric Acid Solution Containing Chloride Ion

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Title: An In Situ Electrochemical Quartz Crystal Microbalance Study of the Dissolution Process of a Gold Electrode in Perchloric Acid Solution Containing Chloride Ion
Authors: Ye, Shen Browse this author
Ishibashi, Chikara Browse this author
Shimazu, Katsuaki Browse this author
Uosaki, Kohei Browse this author →KAKEN DB
Keywords: dissolving
electrochemistry
gold
electrochemical electrodes
electrochemical analysis
microbalances
chemical reactions
Issue Date: 1998
Publisher: The Electrochemical Society
Journal Title: Journal of The Electrochemical Society
Volume: 145
Issue: 5
Start Page: 1614
End Page: 1623
Publisher DOI: 10.1149/1.1838526
Abstract: The anodic dissolution process of a Au(111) oriented electrode in HCl04 solution containing various concentrations of chloride ion was investigated using an electrochemical quartz crystal microbalance (EQCM) under potential sweep and potentiostatic conditions. The in situ EQCM results clearly demonstrated that gold dissolves through a 3e oxidation process in the anodic potential region. No evidence for the 1e- dissolution was obtained in the present study.
Rights: © The Electrochemical Society, Inc. 1998. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in J. Electrochem. Soc. 1998 volume 145, issue 5, 1614-1623.
Type: article
URI: http://hdl.handle.net/2115/50241
Appears in Collections:理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 魚崎 浩平

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