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Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses

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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/57678

Title: Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses
Authors: Konishi, Katsuaki Browse this author →KAKEN DB
Keywords: Absorption spectrum
Chromism
Gold cluster
Optical property
Phosphine
Photoluminescence
Stimuli-responsive materials
Issue Date: 2014
Publisher: Springer-Verlag
Journal Title: Structure and Bonding
Volume: 161
Start Page: 49
End Page: 86
Publisher DOI: 10.1007/430_2014_143
Abstract: Synthetic techniques, geometrical structures, and electronic absorption spectra of phosphine-coordinated pure-gold molecular clusters (PGCs) accumulated over 40 years are comprehensively collected especially for those with unambiguous X-ray crystal structures available. Inspection of the electronic absorption spectra from geometrical aspects reveals that their optical properties are highly dependent on the cluster geometries rather than the nuclearity. Recent examples of unusual clusters that show unique color/photoluminescence properties and their utilization for stimuli-responsive modules are also presented.
Rights: "The original publication is available at www.springerlink.com"
Type: bookchapter (author version)
URI: http://hdl.handle.net/2115/57678
Appears in Collections:環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 小西 克明

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