| Title: | UV-Induced Formation of Ice XI Observed Using an Ultra-High Vacuum Cryogenic Transmission Electron Microscope and its Implications for Planetary Science |
| Authors: | Kouchi, Akira Browse this author →KAKEN DB |
| Kimura, Yuki Browse this author →KAKEN DB |
| Kitajima, Kensei Browse this author →KAKEN DB |
| Katsuno, Hiroyasu Browse this author |
| Hidaka, Hiroshi Browse this author →KAKEN DB |
| Oba, Yasuhiro Browse this author |
| Tsuge, Masashi Browse this author |
| Yamazaki, Tomoya Browse this author |
| Fujita, Kazuyuki Browse this author |
| Hama, Tetsuya Browse this author |
| Takahashi, Yukihiro Browse this author |
| Nakatsubo, Shunichi Browse this author |
| Watanabe, Naoki Browse this author →KAKEN DB |
| Keywords: | ice XI |
| hydrogen atom ordering |
| UV-rays |
| transmission electron microscopy |
| solar system ices |
| Issue Date: | 8-Dec-2021 |
| Publisher: | Frontiers Media |
| Journal Title: | Frontiers in Chemistry |
| Volume: | 9 |
| Start Page: | 799851 |
| Publisher DOI: | 10.3389/fchem.2021.799851 |
| Abstract: | The occurrence of hydrogen atom-ordered form of ice Ih, ice XI, in the outer Solar System has been discussed based on laboratory experiments because its ferroelectricity influences the physical processes in the outer Solar System. However, the formation of ice XI in that region is still unknown due to a lack of formation conditions at temperatures higher than 72 K and the effect of UV-rays on the phase transition from ice I to ice XI. As a result, we observed the UV-irradiation process on ice Ih and ice Ic using a newly developed ultra-high vacuum cryogenic transmission electron microscope. We found that ice Ih transformed to ice XI at temperatures between 75 and 140 K with a relatively small UV dose. Although ice Ic partially transformed to ice XI at 83 K, the rate of transformation was slower than for ice Ih. These findings point to the formation of ice XI at temperatures greater than 72 K via UV irradiation of ice I crystals in the Solar System; icy grains and the surfaces of icy satellites in the Jovian and Saturnian regions. |
| Type: | article |
| URI: | http://hdl.handle.net/2115/83897 |
| Appears in Collections: | 低温科学研究所 (Institute of Low Temperature Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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