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UV-ray irradiation never causes amorphization of crystalline CO2: A transmission electron microscopy study

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Title: UV-ray irradiation never causes amorphization of crystalline CO2: A transmission electron microscopy study
Authors: Masashi, Tsuge Browse this author
Thanh, Nguyen Browse this author →KAKEN DB
Yasuhiro, Oba Browse this author
Hama, Tetsuya Browse this author
Kouchi, Akira Browse this author →KAKEN DB
Watanabe, Naoki Browse this author →KAKEN DB
Keywords: Astrochemistry
Cosmic ice
Transmission electron microscopy
Infrared spectroscopy
Issue Date: 14-Sep-2020
Publisher: Elsevier
Journal Title: Chemical Physics Letters
Volume: 760
Start Page: 137999
Publisher DOI: 10.1016/j.cplett.2020.137999
Abstract: The Crystallinity of ices, amorphous and crystalline, can be altered not only by heat but also by irradiation of UV-rays or charged particles. In this work, the effect of UV-irradiation on the crystallinity of CO2 ice was investigated by using a transmission electron microscope. A crystalline CO2 ice was produced by annealing amorphous CO2 ice. We found that UV-ray irradiation of CO2 crystals at approximately 10 K does not cause amorphization in contrast to the reported amorphization of crystalline water ice below 70 K. We discuss the difference based on the expected UV photochemistry of CO2 ice.
Rights: © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
http://creativecommons.org/licenses/by-nc-nd/4.0/
Type: article (author version)
URI: http://hdl.handle.net/2115/87367
Appears in Collections:低温科学研究所 (Institute of Low Temperature Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 柘植 雅士

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