2024-03-28T08:28:09Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/146252022-11-17T02:08:08Zhdl_2115_20045hdl_2115_139Synthesis of Functionalized Allylsilicone Compounds via Rhodium-Catalyzed Conjugate Addition of (E)- or (Z)-[3-Trimethylsilyl-1-propenyl]boronic Acids to Enones1000030271646Yamamoto, YasunoriFujita, MasayoshiMiyaura, Norioopen accessallylsiliconealkenylboronic acidrhodium catalystconjugate additioncyclobutanol437The rhodium-catalyzed conjugate addition of (E)-Me3SiCH2CH=CHB(OiPr)2 or (Z)-Me3SiCH2(C4H9)C=CHB(OiPr)2 to enones provided a novel method for the synthesis of allylsilicone compounds possessing a carbonyl group in the same molecule, which are versatile intermediates for intramolecular allylsilylation, giving cyclobutanols on treatment with Bu4NF.Georg Thieme Verlag2002-05engjournal articleAMhttp://hdl.handle.net/2115/14625https://doi.org/10.1055/s-2002-253710936-5214Synlett20005767768https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/14625/1/synlett_2002_5_0767.pdfapplication/pdf90.6 KB2002-05