2024-03-29T02:24:24Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/552742022-11-17T02:08:08Zhdl_2115_20059hdl_2115_151High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compoundsJagtap, SachinKaji, YoshinoriFukuoka, Atsushi1000010333593Hara, Kenjiopen accessCreative Commons Attribution 3.0 Unported431A high density monolayer of diisocyanide on gold surface was utilized as a platform of supported Rh catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds. The catalyst exhibited high turnover numbers in a range of 50 000 to 150 000 per Rh atom and showed steady catalyst performance over six recycle usages.Royal Society of Chemistry2014-04engjournal articleVoRhttp://hdl.handle.net/2115/55274https://doi.org/10.1039/c3cc48181f247149781359-73451364-548XChemical Communications5050465048https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/55274/3/c3cc48181f.pdfapplication/pdf1.06 MB2014-04