2024-03-28T22:57:06Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/561612023-08-08T01:24:15Zhdl_2115_20045hdl_2115_139Platinum(0)-Catalyzed Diboration of Methylenecyclopropanes with Bis(pinacolato)diboron: A Selective Route to 2,4-Bis(boryl)-1-butenes1000000232348Ishiyama, TatsuoMomota, Seiji1000010002049Miyaura, Norioopen accessdiboronplatinummethylenecyclopropane430Platinum(0)-catalyzed diboration of methylenecyclopropanes with bis(pinacolato)diboron [(Me4C2O2)B-B(O2C2Me4)] in toluene selectively provided the corresponding 2,4-bis(boryl)-1- butene and its analogs in good yields through the cleavage of the proximal bond of the cyclopropane ring.Georg Thieme Verlag1999-11engjournal articleSMURhttp://hdl.handle.net/2115/56161http://www.thieme-chemistry.com/fileadmin/Thieme/Journals/Synlett/pdf/Thieme_Institutional_Repositories_Nov_2013.pdfhttps://doi.org/10.1055/s-1999-29570936-52141437-2096Synlett19991117901792https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/56161/1/Synlett-1999-2957.pdfapplication/pdf215.18 KB1999-11