2024-03-29T12:24:59Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/638322022-11-17T02:08:08Zhdl_2115_20039hdl_2115_116Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboronMorinaga, AkiraNagao, Kazunori1000040508876Ohmiya, HirohisaSawamura, Masayaopen access"Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron", which has been published in final form at 10.1002/anie.201509218. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving (http://olabout.wiley.com/WileyCDA/Section/id-828039.html).borationBronsted basesdiborylalkenesorganocatalysissynthetic methods400A method for the synthesis of 1,1-diborylalkenes through a Bronsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2-ethynylazoles.Wiley-Blackwell2015-12-21engjournal articleAMhttp://hdl.handle.net/2115/63832https://doi.org/10.1002/anie.201509218265647841433-7851Angewandte chemie-international edition54521585915862https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/63832/2/morinaga_manuscript_revision_2.pdfapplication/pdf279.94 KB2015-12-21