2024-03-29T13:47:43Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/737062022-11-17T02:08:08Zhdl_2115_64361hdl_2115_64360Creating stiff, tough, and functional hydrogel composites with low-melting-point alloysTakahashi, RikuSun, Tao LinSaruwatari, Yoshiyuki1000040451439Kurokawa, TakayukiKing, Daniel R.1000020250417Gong, Jian Pingopen accessThis is the peer reviewed version of the following article: Creating Stiff, Tough, and Functional Hydrogel Composites with Low‐Melting‐Point Alloys, which has been published in final form at https://doi.org/10.1002/adma.201706885. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.composite materialsdouble-network gelshydrogelslow-melting-point alloysthermal responsive materials431Reinforcing hydrogels with a rigid scaffold is a promising method to greatly expand the mechanical and physical properties of hydrogels. One of the challenges of creating hydrogel composites is the significant stress that occurs due to swelling mismatch between the water-swollen hydrogel matrix and the rigid skeleton in aqueous media. This stress can cause physical deformation (wrinkling, buckling, or fracture), preventing the fabrication of robust composites. Here, a simple yet versatile method is introduced to create "macroscale" hydrogel composites, by utilizing a rigid reinforcing phase that can relieve stress-induced deformation. A low-melting-point alloy that can transform from a load-bearing solid state to a free-deformable liquid state at relatively low temperature is used as a reinforcing skeleton, which enables the release of any swelling mismatch, regardless of the matrix swelling degree in liquid media. This design can generally provide hydrogels with hybridized functions, including excellent mechanical properties, shape memory, and thermal healing, which are often difficult or impossible to achieve with single-component hydrogel systems. Furthermore, this technique enables controlled electrochemical reactions and channel-structure templating in hydrogel matrices. This work may play an important role in the future design of soft robots, wearable electronics, and biocompatible functional materials.Wiley-Blackwell2018-04-19engjournal articleAMhttp://hdl.handle.net/2115/73706https://doi.org/10.1002/adma.2017068850935-9648AA10742128Advanced Materials30161706885https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/73706/1/Accepted_LMA%20paper.pdfapplication/pdf3.19 MB2018-04-19