2024-03-28T09:30:06Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/756342022-11-17T02:08:08Zhdl_2115_20045hdl_2115_139脱リンスラグの凝固初期段階における結晶化とリン分配Phosphorous Partition in Dephosphorization Slag Occurring with Crystallization at Initial Stage of Solidificationファン, カンスンPham, Khanh Son1000010169435柏谷, 悦章Kashiwaya, Yoshiakiopen access著作権は日本鉄鋼協会にあるphosphorous partitiondephosphorizationcrystallizationhot thermocouple564Basicity and the amount of FetO were investigated for their effects on the crystallization behavior of the simulated dephosphorizing slags. Twelve kinds of slags were prepared (C/S=1.0–2.5, FetO=10–20%, P2O5=5%). In the present experiment, the Hot Thermocouple Technique was used to melt and quench the samples. After quenching, the microstructure of the slag and the distributions of elements were examined by SEM and EDS analysis.
The diameter of the crystal which precipitated in the sample increased with increasing basicity (C/S) and decreasing FetO content. In addition, glassy regions were observed in the two samples whose FetO content was 20% and whose basicity was 1.0 or 1.5. The samples (10% FetO, 5% P2O5), whose basicity was 1.0 (sample-1) precipitated as a monocalcium silicate (CaO·SiO2); the sample (10% FetO, 5% P2O5) whose basicity was 1.5 (sample-4) precipitated as a dicalcium silicate (2CaO·SiO2). In higher FetO (15–20%) slags, the crystals of the solid solution between 3CaO·P2O5 and 2CaO·SiO2 ((C3P–C2S)ss) were observed. When the amount of CaO increased from C/S=1.5 to C/S=2.5, 2CaO·SiO2 appeared with phosphorous content, but phosphorous was not found in CaO·SiO2.日本鉄鋼協会2009-03-01jpnjournal articleVoRhttp://hdl.handle.net/2115/75634https://doi.org/10.2355/tetsutohagane.95.2410021-15751883-2954AN00151251鉄と鋼953241250https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/75634/3/Tetsu-to-Hagane%2095%283%29_%20241-250%20%282009%29.pdfapplication/pdf4.03 MB2009-03-01