2024-03-28T22:29:27Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/805192022-11-17T02:08:08Zhdl_2115_20059hdl_2115_151Reverse Water-Gas Shift Reaction via Redox of Re Nanoclusters Supported on TiO2Ting, Kah Wei1000030721154Maeno, Zen1000060722650Siddiki, S. M. A. Hakim1000060324000Shimizu, Ken-ichi1000080775388Toyao, Takashimetadata only accessRWGSCO2 hydrogenationRe/TiO2430A Re catalyst supported on TiO2 (Re/TiO2) promoted the reverse water-gas shift (RWGS) reaction, exhibiting high selectivity toward CO. Operando X-ray absorption near edge structure (XANES) measurements revealed that the redox of Re species was responsible for promotion of the reaction. The Re/TiO2 catalyst also possessed remarkable durability and maintained >99.9% CO selectivity for more than 1000 h.日本化学会(Chemical Society of Japan)2021-01engjournal articleNAhttp://hdl.handle.net/2115/80519https://doi.org/10.1246/cl.2006920366-7022Chemistry letters501158161