2024-03-28T15:14:05Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/837652022-11-17T02:08:08Zhdl_2115_20045hdl_2115_139Synthesis of Sulfide Solid Electrolytes from Li2S and P2S5 in AnisoleManiwa, RikuCalpa, MarcelaRosero Navarro, Nataly Carolina1000010603201Miura, Akira1000090244657Tadanaga, Kiyoharuopen access434We report the liquid-phase synthesis of sulfide solid electrolytes from Li2S and P2S5 using anisole at 200–300 °C under microwave radiation, in which -Li3PS4 and Li7P3S11 were directly precipitated in anisole in 30 min. Anisole afforded reasonable reactivity toward Li2S and P2S5 to form -Li3PS4 and Li7P3S11 powders at 200–300 °C. Moreover, a Li6PS5Cl precursor solution was synthesized from a Li3PS4–anisole suspension by adding ethanol, Li2S, and LiCl. The proposed synthesis using anisole is advantageous as a simple, short-time process and would be applicable for the production of all-solid-state batteries.Royal Society of Chemistry2021-01-07engjournal articleAMhttp://hdl.handle.net/2115/83765https://doi.org/10.1039/D0TA08658D2050-74882050-7496Journal of Materials Chemistry A91400405https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/83765/1/Revised%20manuscript_3.pdfapplication/pdf721.46 KB2021-01-07https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/83765/3/Supporting_4.pdfapplication/pdf385.31 KB2021-01-07