2024-03-29T07:28:19Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/851472022-11-17T02:08:08Zhdl_2115_20045hdl_2115_139Discovery of argon in air-hydrate crystals in a deep ice core using scanning electron microscopy and energy-dispersive X-ray spectroscopy1000070356575Uchida, TsutomuShigeyama, WataruOyabu, IkumiGoto-Azuma, KumikoNakazawa, FumioHomma, TomoyukiKawamura, KenjiDahl-Jensen, Dorthemetadata only accessAir hydrateargonenergy-dispersive X-ray spectroscopyNEEM ice corescanning electron microscopy452Tiny samples of ancient atmosphere in air bubbles within ice cores contain argon (Ar), which can be used to reconstruct past temperature changes. At a sufficient depth, the air bubbles are compressed by the overburden pressure under low temperature and transform into air-hydrate crystals. While the oxygen (O-2) and nitrogen (N-2) molecules have indeed been identified in the air-hydrate crystals with Raman spectroscopy, direct observational knowledge of the distribution of Ar at depth within ice sheet and its enclathration has been lacking. In this study, we applied scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) to five air-hydrate crystals in the Greenland NEEM ice core, finding them to contain Ar and N. Given that Ar cannot be detected by Raman spectroscopy, the method commonly used for O-2 and N-2, the SEM-EDS measurement method may become increasingly useful for measuring inert gases in deep ice cores.Cambridge University Press2022-06engjournal articleNAhttp://hdl.handle.net/2115/85147https://doi.org/10.1017/jog.2021.1150022-1430Journal of glaciology68269547556