2024-03-29T15:29:32Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/885502023-03-23T02:40:49Zhdl_2115_20051hdl_2115_144Anion-pi interaction inside the polyanionic Mo132O372 cage with hydrophobic inner spaceMurata, ChinatsuShin, Jaesob1000080234798Konishi, Katsuakimetadata only access431In this paper, we provide experimental evidence to indicate that the polyanionic Mo132O372 cage with a hydrophobic inner nanospace has a unique capability to participate in anion-pi interactions by showing a preference for electron-deficient mono-substituted benzenes over non-electron-deficient guests in inclusion.Royal Society of Chemistry2023-02-28engjournal articleNAhttp://hdl.handle.net/2115/88550https://doi.org/10.1039/d2cc06875c1359-73451364-548XAA11071130Chemical Communications591724412444