2024-03-28T09:28:14Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/158372022-11-17T02:08:08Zhdl_2115_20045hdl_2115_139Asymmetric hydrogenation of 1-phenylethenylboronic acid and esters for the synthesis of chiral organoboron compoundsUeda, MasatoSaitoh, AtsushiMiyaura, NorioHydrogenationAsymmetric synthesisBoron and compounds437The hydrogenation of ethanediol 1-phenylethenylboronic ester was carried out at −20 °C under a hydrogen atmosphere (9 atm) in the presence of [Rh(cod)2]BF4–(R)-BINAP (3 mol%). After alkaline hydrogen peroxide oxidation, the reaction gave 1-phenylethanol with 80% e.e.Elsevier Science B.V.Journal Articleapplication/pdfhttp://hdl.handle.net/2115/15837https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/15837/1/JOC642-1-2.pdf0022-328X0022-328XJournal of Organometallic Chemistry6421-21451472002-01-18enginfo:doi/10.1016/S0022-328X(01)01239-6author