2024-03-29T13:22:18Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/441692022-11-17T02:08:08Zhdl_2115_20051hdl_2115_144Intramolecular Glycosylation Approach toward Constructing the Macrocyclic Structure of Resin GlycosidesSon, Sang-HyunYamagiya, NatsukoFurukawa, Jun-ichiSakairi, Nobuo樹脂配糖体resin glycosideマクロライドmacrolideトリコロリンtricolorin分子内グリコシル化反応intramolecular glycosylationドデシルチオグリコシドDodecyl thioglycoside431Oligosaccharide containing macrolides of resin glycosides were effectively constructed by MeOTf promoted intramolecular glycosylation of dodecyl thioglycosyl donors. Synthesis of a key disaccharide intermediate of tricolorin A and total synthesis of tricolorin F were successfully achieved by this approach.Georg Thieme VerlagJournal Articleapplication/pdfhttp://hdl.handle.net/2115/44169https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/44169/1/Sakairi_Synlett2009.pdf0936-5214AA10731110Synlett200918295729602009-11enginfo:doi/10.1055/s-0029-1218272© 2009 Georg Thieme Verlagauthor