2024-03-28T19:20:06Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/456012022-11-17T02:08:08Zhdl_2115_20039hdl_2115_116Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chainsKiriya, DaisukeNakamura, KoheiKitagawa, SusumuChang, Ho-Chol431Functionalization of a cobalt/dioxolene complex with branched, asymmetric alkyl chains promotes non-cooperative and cooperative valence tautomerisms synchronized with thermodynamically favoured crystal-to-melt and kinetically generated glass-to-melt phase transitions, respectively, depending on the degree of crystallinity.Royal Society of ChemistryJournal Articleapplication/pdfhttp://hdl.handle.net/2115/45601https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/45601/1/CC46-21_3729-3731.pdf1359-7345Chemical Communications4621372937312010-06-07enginfo:doi/10.1039/c001568gChem. Commun., 2010, 46, 3729-3731 - Reproduced by permission of The Royal Society of Chemistry (RSC)author