2024-03-28T23:32:17Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/537602022-11-17T02:08:08Zhdl_2115_20059hdl_2115_151Direct bromination of hydrocarbons catalyzed by Li2MnO3 under oxygen and photo-irradiation conditionsNishina, YutaMorita, JunyaOhtani, Bunsho431A method for the direct bromination of hydrocarbons with Br2 using a ubiquitous and inexpensive catalyst is highly desirable. Herein, we report the selective monobromination of hydrocarbons in good yield using Li2MnO3 as a catalyst under irradiation with a fluorescent room light. This new catalyst can be recyclable. The effect of light was investigated using action spectra, which revealed that the reaction occurred on the surface of the catalyst.Royal Society of ChemistryJournal Articleapplication/pdfapplication/pdfhttp://hdl.handle.net/2115/53760https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/53760/2/RSCA3-7_2158-2162.pdfhttps://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/53760/1/Supplementary_information.pdf2046-2069RSC Advances37215821622013enginfo:doi/10.1039/c2ra22197gRSC Adv., 2013,3, 2158-2162 - Reproduced by permission of The Royal Society of Chemistry (RSC)author