2024-03-28T10:53:19Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/778102022-11-17T02:08:08Zhdl_2115_20045hdl_2115_139Decarbonylation through Aldehydic C–H Bond Cleavage by a Cationic Iridium CatalystShirai, TomohikoSugimoto, KazukiIwasaki, MasayaSumida, RyukiFujita, HarunoriYamamoto, Yasunoridecarbonylationiridium catalysisaldehydesC–H bond cleavageasymmetric catalysishydroacylationWe report the decarbonylation of aldehydes through an aldehydic C–H bond cleavage catalyzed by a cationic iridium/bisphosphine catalyst. The reaction proceeds under relatively mild conditions to give the corresponding hydrocarbon products in moderate to high yields. In addition, this cationic iridium catalyst system can be applied to an asymmetric hydroacylation of ketones.Georg ThiemeJournal Articleapplication/pdfhttp://hdl.handle.net/2115/77810https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/77810/1/Synlett30%2808%29972-976-AcceptedVersion20190322.pdf0936-5214AA10731110Synlett30089729762019-05enginfo:doi/10.1055/s-0037-1611802author