2024-03-28T20:16:17Zhttps://eprints.lib.hokudai.ac.jp/dspace-oai/requestoai:eprints.lib.hokudai.ac.jp:2115/789992022-11-17T02:08:08Zhdl_2115_20044hdl_2115_124Cp*Co (III) -Catalyzed C-H Functionalization and Asymmetric Reactions Using External Chiral SourcesYoshino, TatsuhikoMatsunaga, ShigekiC-H functionalizationC-H activationcobaltrhodiumasymmetric catalysis460This account describes Cp*Co-III-catalyzed C-H functionalization reactions developed in our group between 2013 and 2018. Cp*Co-III-catalysts not only serve as inexpensive alternatives to Cp*Rh-III catalysts but also exhibit unique reactivity and selectivity in several transformations. In the latter part of this review, we introduce catalytic asymmetric C-H functionalization reactions using achiral Rh-III or Co-III catalysts with chiral disulfonates or carboxylic acids as external chiral sources.Georg Thieme VerlagJournal Articleapplication/pdfhttp://hdl.handle.net/2115/78999https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/78999/1/WoS_90275_Yoshino.pdf0936-5214Synlett3012138414002019-07enginfo:doi/10.1055/s-0037-1611814author