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Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Direct observation and reactions of Cl3 radical
| Title: | Direct observation and reactions of Cl3 radical |
| Authors: | Enami, Shinichi Browse this author | | Yamanaka, Takashi Browse this author | | Hashimoto, Satoshi Browse this author | | Kawasaki, Masahiro Browse this author | | Aloisio, Simone Browse this author | | Tachikawa, Hiroto Browse this author →KAKEN DB |
| Issue Date: | 7-Oct-2006 |
| Publisher: | American Institute of Physics |
| Journal Title: | The Journal of Chemical Physics |
| Volume: | 125 |
| Issue: | 133116 |
| Publisher DOI: | 10.1063/1.2217440 |
| PMID: | 17029442 |
| Abstract: | The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+Cl3. ©2006 American Institute of Physics |
| Rights: | Copyright © 2006 American Institute of Physics |
| Relation: | http://jcp.aip.org/jcp/top.jsp |
| Type: | article |
| URI: | http://hdl.handle.net/2115/14881 |
| Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 田地川 浩人
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