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Direct observation and reactions of Cl3 radical

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Title: Direct observation and reactions of Cl3 radical
Authors: Enami, Shinichi Browse this author
Yamanaka, Takashi Browse this author
Hashimoto, Satoshi Browse this author
Kawasaki, Masahiro Browse this author
Aloisio, Simone Browse this author
Tachikawa, Hiroto Browse this author →KAKEN DB
Issue Date: 7-Oct-2006
Publisher: American Institute of Physics
Journal Title: The Journal of Chemical Physics
Volume: 125
Issue: 133116
Publisher DOI: 10.1063/1.2217440
PMID: 17029442
Abstract: The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+Cl3. ©2006 American Institute of Physics
Rights: Copyright © 2006 American Institute of Physics
Type: article
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 田地川 浩人

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