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Cross-coupling reaction of organoboron compounds via base-assisted transmetalation to palladium(II) complexes

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Title: Cross-coupling reaction of organoboron compounds via base-assisted transmetalation to palladium(II) complexes
Authors: Miyaura, Norio Browse this author
Keywords: Cross-coupling
Organoboron compounds
Palladium(II) complexes
Issue Date: 1-Jul-2002
Publisher: Elsevier Science B.V.
Journal Title: Journal of Organometallic Chemistry
Volume: 653
Issue: 1-2
Start Page: 54
End Page: 57
Publisher DOI: 10.1016/S0022-328X(02)01264-0
Abstract: Until recently, organoboronic acids have been of limited use in organic synthesis due to their low reactivity for ionic reactions. During the past two decades; however, it has become increasingly clear that they are valuable reagents capable of undergoing many carbon–carbon bond formations in organic syntheses. In 1979, catalytic carbon–carbon bond formation, via transmetalation between organoboron compounds and palladium(II) halides, was found to proceed in the presence of a base.
Relation URI: http://www.sciencedirect.com/science/journal/0022328X
Type: article (author version)
URI: http://hdl.handle.net/2115/15835
Appears in Collections:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 宮浦 憲夫

 

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