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Synthesis of 2-Substituted Cyclohexene Derivatives through Cross-Coupling Reactions via π-Allylmetal Intermediate Using N-Heterocyclic Carbenes (NHCs) as Ligands

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タイトル: Synthesis of 2-Substituted Cyclohexene Derivatives through Cross-Coupling Reactions via π-Allylmetal Intermediate Using N-Heterocyclic Carbenes (NHCs) as Ligands
著者: Yamazaki, Tetsuro 著作を一覧する
Sato, Yoshihiro 著作を一覧する
キーワード: N-heterocyclic carbene (NHC)
cross-coupling
Migita-Kosugi-Stille reaction
Kumada-Tamao-Coriiu reaction
palladium
nickel
発行日: 2008年 9月
出版者: Georg Thieme Verlag KG
誌名: Synthesis : international journal of methods in synthetic organic chemistry
巻: 2008
号: 17
開始ページ: 2830
終了ページ: 2834
出版社 DOI: 10.1055/s-2008-1067222
抄録: Palladium- or nickel-catalyzed cross-coupling reactions of 2-substituted cyclohexenes, which are generally less reactive than those having no substituent at the C2 position, with organotin reagents (Migita-Kosugi-Stille coupling) or with Grigard reagents (Kumada-Tamao-Corriu coupling) using a NHC as a ligand was investigated. It was found that NHCs are effective as ligands for these reactions, giving the corresponding cross-coupling products in good yields.
Rights: © 2008 Georg Thieme Verlag KG.
資料タイプ: article (author version)
URI: http://hdl.handle.net/2115/39134
出現コレクション:雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

提供者: 佐藤 美洋

 

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