A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides


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Please use this identifier to cite or link to this item:http://hdl.handle.net/2115/44006

Title:	A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
Authors:	Miyaura, Norio Browse this author
	Yamada, Kinji Browse this author
	Suzuki, Akira Browse this author →KAKEN DB
Issue Date:	1979
Publisher:	Pergamon Press
Journal Title:	Tetrahedron Letters
Volume:	20
Issue:	36
Start Page:	3437
End Page:	3440
Publisher DOI:	10.1016/S0040-4039(01)95429-2
Abstract:	The representative (E)-1-alkenyldisiamylboranes and (E)-1-alkenyl-1,3,2-benzodioxaboroles readily obtainable Image hydroboration of 1-alkynes react with 1-alkenyl halides or 1-alkynyl halides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and base to give corresponding conjugated (E)-dienes or (E)-enynes with high regio- and stereospecificity in good yields, respectively.
Description:	This article is related to the Nobel Prize in chemistry 2010
Rights:	This posting is granted exceptional permission by the owner of copyright.
Type:	article
URI:	http://hdl.handle.net/2115/44006
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 宮浦憲夫

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