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A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides

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Title: A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides
Authors: Miyaura, Norio Browse this author
Yamada, Kinji Browse this author
Suzuki, Akira Browse this author →KAKEN DB
Issue Date: 1979
Publisher: Pergamon Press
Journal Title: Tetrahedron Letters
Volume: 20
Issue: 36
Start Page: 3437
End Page: 3440
Publisher DOI: 10.1016/S0040-4039(01)95429-2
Abstract: The representative (E)-1-alkenyldisiamylboranes and (E)-1-alkenyl-1,3,2-benzodioxaboroles readily obtainable Image hydroboration of 1-alkynes react with 1-alkenyl halides or 1-alkynyl halides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and base to give corresponding conjugated (E)-dienes or (E)-enynes with high regio- and stereospecificity in good yields, respectively.
Description: This article is related to the Nobel Prize in chemistry 2010
Rights: This posting is granted exceptional permission by the owner of copyright.
Type: article
URI: http://hdl.handle.net/2115/44006
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 宮浦 憲夫

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