Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes


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Title:	Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes
Authors:	Ohmiya, Hirohisa Browse this author
	Yoshida, Mika Browse this author
	Sawamura, Masaya Browse this author →KAKEN DB
Keywords:	pyrrolidines
	piperidines
	protecting-group-free synthesis
	hydroamination
	copper
Issue Date:	Sep-2010
Publisher:	Georg Thieme Verlag
Journal Title:	Synlett
Volume:	2010
Issue:	14
Start Page:	2136
End Page:	2140
Publisher DOI:	10.1055/s-0030-1258527
Abstract:	An efficient approach to hydroxylated pyrrolidine and piperidine derivatives through the intramolecular hydroamination catalyzed by a Cu(I)-Xantphos system is described. The transformation allows for the short synthesis of N-alkylated azasugars without a protection/deprotection event of the hydroxy groups.
Rights:	© 2010 Georg Thieme Verlag
Type:	article (author version)
URI:	http://hdl.handle.net/2115/47035
Appears in Collections:	理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 澤村正也

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