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Determination of SDS Using Fluorescent γ-Cyclodextrin Based on TICT in Aqueous Solution
Title: | Determination of SDS Using Fluorescent γ-Cyclodextrin Based on TICT in Aqueous Solution |
Authors: | Oka, Yoshikazu Browse this author | Nakamura, Shinnosuke Browse this author | Uetani, Yusuke Browse this author | Morozumi, Tatsuya Browse this author →KAKEN DB | Nakamura, Hiroshi Browse this author →KAKEN DB |
Issue Date: | Oct-2012 |
Publisher: | Japan Society for Analytical Chemistry |
Journal Title: | Analytical Sciences |
Volume: | 28 |
Issue: | 10 |
Start Page: | 973 |
End Page: | 978 |
Publisher DOI: | 10.2116/analsci.28.973 |
Abstract: | Fluorescent γ-cyclodextrin derivatives, modified using N-phenyl-x-anthracenecarboxamido (ACs; x = 9, 1), were synthesized and investigated using fluorescence and UV-vis spectroscopy. Fluorescence enhancements of ACs were observed up to 12-fold by the addition of sodium dodecyl sulfate (SDS) below the critical micellar concentration (CMC). In the presence of a nonionic surfactant, such as Triton X-100, fluorescence spectra were scarcely changed. The fluorescence selectivity between SDS and Triton X-100 was clarified from the different spectral behaviors by circular dichroism and 1H NMR spectroscopies. |
Type: | article |
URI: | http://hdl.handle.net/2115/50794 |
Appears in Collections: | 環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 中村 博
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