A synthesis of allylboronates via the palladium(0)-catalyzed cross-coupling reaction of bis(pinacolato)diboron with allylic acetates


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Title:	A synthesis of allylboronates via the palladium(0)-catalyzed cross-coupling reaction of bis(pinacolato)diboron with allylic acetates
Authors:	Ishiyama, Tatsuo Browse this author →KAKEN DB
	Ahiko, Taka-aki Browse this author
	Miyaura, Norio Browse this author →KAKEN DB
Issue Date:	16-Sep-1996
Publisher:	Elsevier
Journal Title:	Tetrahedron Letters
Volume:	37
Issue:	38
Start Page:	6889
End Page:	6892
Publisher DOI:	10.1016/0040-4039(96)01505-5
Abstract:	The cross-coupling reaction of bis(pinacolato)diboron [(Me4C202 )BB( O2C2Me4) ] with allyl acetates regio- and E-stereoselectively provided the pinacol esters of allylboronic acids in high yields. The reaction was efficiently catalyzed by Pd(dba) 2 in DMSO at 50 °C.
Type:	article (author version)
URI:	http://hdl.handle.net/2115/56158
Appears in Collections:	工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山竜生

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