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Transition metal-catalyzed borylation of alkanes and arenes via C-H activation

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Title: Transition metal-catalyzed borylation of alkanes and arenes via C-H activation
Authors: Ishiyama, Tatsuo Browse this author →KAKEN DB
Miyaura, Norio Browse this author →KAKEN DB
Keywords: Transition metal complexes
Bis(pinacolato)diboron
Pinacolborane
Hydrocarbon
Organoboron compound
C -H borylation
Issue Date: 29-Aug-2003
Publisher: Elsevier
Journal Title: Journal of Organometallic Chemistry
Volume: 680
Issue: 1-2
Start Page: 3
End Page: 11
Publisher DOI: 10.1016/S0022-328X(03)00176-1
Abstract: Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by several groups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety of organoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed C -H borylation of alkanes, arenes and benzylic positions of alkylarenes by bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via C -H activation are summarized.
Type: article (author version)
URI: http://hdl.handle.net/2115/56230
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 石山 竜生

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