Hokkaido University Collection of Scholarly and Academic Papers >
Graduate School of Engineering / Faculty of Engineering >
Peer-reviewed Journal Articles, etc >
Transition metal-catalyzed borylation of alkanes and arenes via C-H activation
Title: | Transition metal-catalyzed borylation of alkanes and arenes via C-H activation |
Authors: | Ishiyama, Tatsuo Browse this author →KAKEN DB | Miyaura, Norio Browse this author →KAKEN DB |
Keywords: | Transition metal complexes | Bis(pinacolato)diboron | Pinacolborane | Hydrocarbon | Organoboron compound | C -H borylation |
Issue Date: | 29-Aug-2003 |
Publisher: | Elsevier |
Journal Title: | Journal of Organometallic Chemistry |
Volume: | 680 |
Issue: | 1-2 |
Start Page: | 3 |
End Page: | 11 |
Publisher DOI: | 10.1016/S0022-328X(03)00176-1 |
Abstract: | Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by several groups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety of organoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed C -H borylation of alkanes, arenes and benzylic positions of alkylarenes by bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via C -H activation are summarized. |
Type: | article (author version) |
URI: | http://hdl.handle.net/2115/56230 |
Appears in Collections: | 工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
|
Submitter: 石山 竜生
|