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Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses
Title: | Phosphine-Coordinated Pure-Gold Clusters: Diverse Geometrical Structures and Unique Optical Properties/Responses |
Authors: | Konishi, Katsuaki Browse this author →KAKEN DB |
Keywords: | Absorption spectrum | Chromism | Gold cluster | Optical property | Phosphine | Photoluminescence | Stimuli-responsive materials |
Issue Date: | 2014 |
Publisher: | Springer-Verlag |
Journal Title: | Structure and Bonding |
Volume: | 161 |
Start Page: | 49 |
End Page: | 86 |
Publisher DOI: | 10.1007/430_2014_143 |
Abstract: | Synthetic techniques, geometrical structures, and electronic absorption spectra of phosphine-coordinated pure-gold molecular clusters (PGCs) accumulated over 40 years are comprehensively collected especially for those with unambiguous X-ray crystal structures available. Inspection of the electronic absorption spectra from geometrical aspects reveals that their optical properties are highly dependent on the cluster geometries rather than the nuclearity. Recent examples of unusual clusters that show unique color/photoluminescence properties and their utilization for stimuli-responsive modules are also presented. |
Rights: | "The original publication is available at www.springerlink.com" |
Type: | bookchapter (author version) |
URI: | http://hdl.handle.net/2115/57678 |
Appears in Collections: | 環境科学院・地球環境科学研究院 (Graduate School of Environmental Science / Faculty of Environmental Earth Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 小西 克明
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