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Copper-Catalyzed gamma-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes
| Title: | Copper-Catalyzed gamma-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes |
| Authors: | Yasuda, Yuto Browse this author | | Nagao, Kazunori Browse this author | | Shido, Yoshinori Browse this author | | Mori, Seiji Browse this author | | Ohmiya, Hirohisa Browse this author →KAKEN DB | | Sawamura, Masaya Browse this author →KAKEN DB |
| Keywords: | allylic substitution | | copper catalysis | | coupling | | secondary alkylborane | | stereoselectivity |
| Issue Date: | 26-Jun-2015 |
| Publisher: | Wiley-Blackwell |
| Journal Title: | Chemistry - A European Journal |
| Volume: | 21 |
| Issue: | 27 |
| Start Page: | 9666 |
| End Page: | 9670 |
| Publisher DOI: | 10.1002/chem.201501055 |
| PMID: | 26013036 |
| Abstract: | The scope of the copper-catalyzed coupling reactions between organoboron compounds and allylic phosphates is expanded significantly by employing triphenylphosphine as a ligand for copper, allowing the use of secondary alkylboron compounds. The reaction proceeds with complete gamma-E-selectivity and preferential 1,3-syn stereoselectivity. The reaction of gamma-silicon-substituted allylic phosphates affords enantioenriched alpha-stereogenic allylsilanes. |
| Rights: | This is the peer reviewed version of the following article: [Yuto Yasuda et al.,Copper-Catalyzed γ-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes. Chemistry - A European Journal, 21(27), p.9666–9670, 2015], which has been published in final form at [http://doi.org/10.1002/chem.201501055]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
| Type: | article (author version) |
| URI: | http://hdl.handle.net/2115/62278 |
| Appears in Collections: | 理学院・理学研究院 (Graduate School of Science / Faculty of Science) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)
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Submitter: 澤村 正也
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