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A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism

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Title: A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism
Authors: Seki, Tomohiro Browse this author →KAKEN DB
Kobayashi, Koh Browse this author
Mashimo, Takaki Browse this author
Ito, Hajime Browse this author →KAKEN DB
Issue Date: 11-Oct-2018
Publisher: Royal Society of Chemistry
Journal Title: Chemical communications
Volume: 54
Issue: 79
Start Page: 11136
End Page: 11139
Publisher DOI: 10.1039/c8cc06490c
Abstract: The epistatic double hydrogen bonds that arise from the presence of a pendant carboxy group in a gold isocyanide complex result in strong aurophilic interactions in a magenta-emitting polymorph. This is due to the lack of the typically antiparallel dimer arrangements, which often prevent the formation of strong aurophilic interactions. Furthermore, this polymorph shows hypsochromically shifted luminescence mechanochromism.
Type: article (author version)
URI: http://hdl.handle.net/2115/75750
Appears in Collections:工学院・工学研究院 (Graduate School of Engineering / Faculty of Engineering) > 雑誌発表論文等 (Peer-reviewed Journal Articles, etc)

Submitter: 関 朋宏

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