open access

https://hdl.handle.net/2115/100470

Combustion Reactions between Transition-Metal Chlorides and Sodium Amide and Their Ignition Temperature

英語

2021-08-24

American Chemical Society (ACS)

Inorganic Chemistry

60(17)

12753-12758

Combustion reactions between metal chlorides and sodium amide proceed in a short time; however, these reactions must be carried out with appropriate safety measures. Investigating their ignition temperatures would facilitate safe handling and give kinetic insights about the reaction between powders. Here, we investigated the products of the reactions between metal chlorides and sodium amide and measured their ignition temperatures. The products were mainly composed of nitrides, metals, and sodium chloride. The reactions of 4d and 5d metal chlorides initiated the reaction below room temperature, while 3d metal chlorides, except copper chloride, initiated the reaction upon heating. We found the correlation between the ignition temperatures and the reaction energies of the combustion reaction.

学術雑誌論文

Accepted Manuscript

This document is the Accepted Manuscript version of a Published Article that appeared in final form in Combustion Reactions between Transition-Metal Chlorides and Sodium Amide and Their Ignition Temperature, copyright © 2021 American Chemical Society. To access the final published article, see ACS Articles on Request.

0020-1669

1520-510X