Direct observation and reactions of Cl3 radical

Enami, Shinichi; Yamanaka, Takashi; Hashimoto, Satoshi et al.

The Journal of Chemical Physics, 2006, 125(133116)

Permalink : https://hdl.handle.net/2115/14881

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アクセス権	open access
URI	https://hdl.handle.net/2115/14881
タイトル	Direct observation and reactions of Cl3 radical
著者	Enami, Shinichi ; Yamanaka, Takashi ; Hashimoto, Satoshi ; Kawasaki, Masahiro ; Aloisio, Simone ; Tachikawa, Hiroto
著者名 Enami, Shinichi
著者名 Yamanaka, Takashi
著者名 Hashimoto, Satoshi
著者名 Kawasaki, Masahiro
著者名 Aloisio, Simone
e-Rad_Researcher 10207045 著者名 Tachikawa, Hiroto
言語	英語
発行日	2006-10-07
出版者	American Institute of Physics
収録物名	The Journal of Chemical Physics
巻(号)	125(133116)
抄録	The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+Cl3. ©2006 American Institute of Physics
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
権利情報	Copyright © 2006 American Institute of Physics
PISSN	0021-9606
関連情報	PMID 17029442
関連情報	URI http://jcp.aip.org/jcp/top.jsp
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1063/1.2217440