Reaction of CS2/Cl complexes with alcohols studied by pulse radiolysis

Sumiyoshi, Takashi; Nakayama, Masayosi; Fujiyoshi, Ryoko et al.

Radiation Physics and Chemistry, 2005, 74(5), 317-322

Permalink : https://hdl.handle.net/2115/15413

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アクセス権	open access
URI	https://hdl.handle.net/2115/15413
タイトル	Reaction of CS2/Cl complexes with alcohols studied by pulse radiolysis
著者	Sumiyoshi, Takashi ; Nakayama, Masayosi ; Fujiyoshi, Ryoko ; Sawamura, Sadashi
e-Rad_Researcher 90002211 著者名 Sumiyoshi, Takashi
著者名 Nakayama, Masayosi
著者名 Fujiyoshi, Ryoko
著者名 Sawamura, Sadashi
言語	英語
キーワード	CS2/Cl complex
	Hydrogen abstraction
	Selectivity
	Pulse radiolysis
発行日	2005-12
出版者	Elsevier
収録物名	Radiation Physics and Chemistry
巻(号)	74(5)
ページ	317-322
抄録	The reactivity and selectivity of carbon disulfide-chlorine atom complex (CS2/Cl) for hydrogen atom abstraction from various alcohols were studied by pulse radiolysis technique in carbon tetrachloride at room temperature. The measured absolute rate constants were in the range from 4.0×106 for methanol to 3.5×107 dm3 mol−1 s−1 for cyclopentanol. The hydrogen abstraction selectivity was calculated based on the analysis of partial reactivities. The tertiary/primary selectivities were determined to be 8.2 for α-position and 6.8 for β-position of alcohols.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	0969-806X
関連情報	URI http://www.sciencedirect.com/science/journal/0969806X
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/j.radphyschem.2005.02.008