Stereoselective Synthesis of 5-7 membered Cyclic Ethers by Deiodonative Ring-Enlargement Using Hypervalent Iodine Reagents

Abo, Tomohito; Sawaguchi, Masanori; Senboku, Hisanori et al.

Molecules, 2005, 10(1), 183-189

Permalink : https://hdl.handle.net/2115/15850

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URI	https://hdl.handle.net/2115/15850
タイトル	Stereoselective Synthesis of 5-7 membered Cyclic Ethers by Deiodonative Ring-Enlargement Using Hypervalent Iodine Reagents
著者	Abo, Tomohito ; Sawaguchi, Masanori ; Senboku, Hisanori ; Hara, Shoji
著者名 Abo, Tomohito
著者名 Sawaguchi, Masanori
著者名 Senboku, Hisanori
著者名 Hara, Shoji
言語	英語
キーワード	Ring-enlargement
	cyclic ether
	hypervalent iodine compounds
発行日	2005-01
出版者	MOLECULAR DIVERSITY PRESERVATION International (MDPI)
収録物名	Molecules
巻(号)	10(1)
ページ	183-189
抄録	Stereoselective synthesis of 5-7 membered cyclic ethers was achieved by deiodonative ring-enlargement of cyclic ethers having an iodoalkyl substituent. The reaction took place readily under mild conditions using hypervalent iodine compounds and an acetoxy or a trifluoroacetoxy group was introduced into the rings depending on the hypervalent iodine reagent employed. The use of hexafluoroisopropanol (HFIP) as solvent is critical.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
PISSN	1420-3049
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.3390/10010183