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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/20537
タイトル	Photoanodic formation of an organic monolayer on a hydrogen-terminated Si(111) surface via Si–C covalent bond using a Grignard reagent and its application for one-step monolayer-patterning
著者	Takakusagi, Satoru ; Miyasaka, Toyomitsu ; Uosaki, Kohei
e-Rad_Researcher 30359484 著者名 Takakusagi, Satoru
著者名 Miyasaka, Toyomitsu
著者名 Uosaki, Kohei
言語	英語
キーワード	Semiconductor electrode
	Photoelectrochemistry
	Grignard
	Organic monolayer
	Silicon
	Patterning
発行日	2007-01-15
出版者	Elsevier
収録物名	Journal of Electroanalytical Chemistry
巻(号)	599(2)
ページ	344-348
抄録	Alkyl monolayer (octadecyl) was formed on a hydrogen-terminated Si(1 1 1) (H–Si(1 1 1)) electrode via Si–C covalent bond by photoanodic reaction with C18H37MgCl in THF solution. The formation of the organic monolayer was confirmed by attenuated total reflection (ATR) FT-IR spectroscopy. This process was applied to a one-step patterning of an organic monolayer on a H–Si(1 1 1) by illuminating the H–Si(1 1 1) electrode through photomask in a C18H37MgCl/THF solution at positive potential. The formation of the pattern reflecting the shape of the photomask was confirmed by SEM observations.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	0022-0728
EISSN	0022-0728
関連情報	URI http://www.sciencedirect.com/science/journal/00220728
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/j.jelechem.2006.06.004

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