Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates

Yamawaki, Minoru; Tanaka, Masahiko; Abe, Takumi et al.

Heterocycles - An International Journal for Reviews and Communications in Heterocyclic Chemistry, 2007, 72, 709-721

Permalink : https://hdl.handle.net/2115/26427

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アクセス権	open access
URI	https://hdl.handle.net/2115/26427
タイトル	Catalytic Enantioselective Aziridination of Alkenes Using Chiral Dirhodium(II) Carboxylates
著者	Yamawaki, Minoru ; Tanaka, Masahiko ; Abe, Takumi ; Anada, Masahiro ; Hashimoto, Shunichi
著者名 Yamawaki, Minoru
著者名 Tanaka, Masahiko
著者名 Abe, Takumi
e-Rad_Researcher 90344473 著者名 Anada, Masahiro
e-Rad_Researcher 80107391 著者名 Hashimoto, Shunichi
言語	英語
発行日	2007-04-13
出版者	The Japan Institute of Heterocyclic Chemistry
収録物名	Heterocycles - An International Journal for Reviews and Communications in Heterocyclic Chemistry
巻(号)	72
ページ	709-721
抄録	The enantioselective aziridination of alkenes with [N-(4-nitrophenylsulfonyl)imino]phenyliodinane catalyzed by dirhodium(II) tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinate], Rh2(S-TCPTTL)4, is described. While such enantioselectivities are highly dependent on the properties of the alkenes, 2,2-dimethylchromene was found to be a particularly suitable substrate which can be efficiently transformed into the aziridine product in 98% yield with 94% ee.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	0385-5414