Dirhodium(II) Tetrakis[N-benzene-fused Phthaloyl-(S)-piperidinonate] as a Chiral Lewis Acid: Catalytic Enantioselective Aldol Reactions of Acetate-derived Silylketene Acetals and Aldehydes

Washio, Takuya; Nakamura, Seiichi; Anada, Masahiro et al.

Heterocycles - An International Journal for Reviews and Communications in Heterocyclic Chemistry, 2005, 66(1), 567-578

Permalink : https://hdl.handle.net/2115/26430

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URI	https://hdl.handle.net/2115/26430
タイトル	Dirhodium(II) Tetrakis[N-benzene-fused Phthaloyl-(S)-piperidinonate] as a Chiral Lewis Acid: Catalytic Enantioselective Aldol Reactions of Acetate-derived Silylketene Acetals and Aldehydes
著者	Washio, Takuya ; Nakamura, Seiichi ; Anada, Masahiro ; Hashimoto, Shunichi
著者名 Washio, Takuya
著者名 Nakamura, Seiichi
e-Rad_Researcher 90344473 著者名 Anada, Masahiro
e-Rad_Researcher 80107391 著者名 Hashimoto, Shunichi
言語	英語
発行日	2005-12-31
出版者	The Japan Institute of Heterocyclic Chemistry
収録物名	Heterocycles - An International Journal for Reviews and Communications in Heterocyclic Chemistry
巻(号)	66(1)
ページ	567-578
抄録	A first example of chiral dirhodium(II) complex-catalyzed enantioselective Mukaiyama aldol reactions is described. The aldol addition reaction of methyl acetate-derived trimethylsilylketene acetal with specific aldehydes such as benzyloxyacetaldehyde and electron-poor aromatic aldehydes is effectively catalyzed by dirhodium(II) tetrakis[N-benzene-fused phthaloyl-(S)- piperidinonate] (1a), providing silylated aldol adducts in up to 94% ee.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	0385-5414
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.3987/com-05-s(k)25