Surface species studied by angle-resolved product desorption : Emission mechanism and spatial distribution

Matsushima, Tatsuo

Surface Science, 2009, 603(10-12), 1415-1426

Permalink : https://hdl.handle.net/2115/38730

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アクセス権	open access
URI	https://hdl.handle.net/2115/38730
タイトル	Surface species studied by angle-resolved product desorption : Emission mechanism and spatial distribution
著者	e-Rad_Researcher 30002116 著者名 Matsushima, Tatsuo
言語	英語
キーワード	Desorption dynamics
	Angle resolved TPD
	Surface chemical reaction
	Nitrogen oxides
	Carbon monoxide
	Palladium
	Platinum
	Rhodium
発行日	2009-06-01
出版者	Elsevier B.V.
収録物名	Surface Science
巻(号)	603(10-12)
ページ	1415-1426
抄録	Recent progress and future developments in angle-resolved measurements of desorbing surface reaction products are reviewed for the analysis of surface species. Spatial and energy distributions of desorbing products with hyperthermal energy deliver the most direct structural information of the transition state including active intermediates and product formation sites. Knowledge of the desorption mechanism is requisite to achieve structural information since the method is directly linked to the chemical process. Structural analyses are exemplified in photoinduced O2 desorption and CO oxidation, and compared with those from thermal N2O decomposition and CO oxidation as well as their applications to steady-state catalytic processes.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	0039-6028
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/j.susc.2008.10.053