Synthesis of 2-Substituted Cyclohexene Derivatives through Cross-Coupling Reactions via π-Allylmetal Intermediate Using N-Heterocyclic Carbenes (NHCs) as Ligands

Yamazaki, Tetsuro; Sato, Yoshihiro

Synthesis : international journal of methods in synthetic organic chemistry, 2008, 2008(17), 2830-2834

Permalink : https://hdl.handle.net/2115/39134

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アクセス権	open access
URI	https://hdl.handle.net/2115/39134
タイトル	Synthesis of 2-Substituted Cyclohexene Derivatives through Cross-Coupling Reactions via π-Allylmetal Intermediate Using N-Heterocyclic Carbenes (NHCs) as Ligands
著者	著者名 Yamazaki, Tetsuro
著者	著者名 Sato, Yoshihiro
言語	英語
キーワード	N-heterocyclic carbene (NHC)
	cross-coupling
	Migita-Kosugi-Stille reaction
	Kumada-Tamao-Coriiu reaction
	palladium
	nickel
発行日	2008-09
出版者	Georg Thieme Verlag KG
収録物名	Synthesis : international journal of methods in synthetic organic chemistry
巻(号)	2008(17)
ページ	2830-2834
抄録	Palladium- or nickel-catalyzed cross-coupling reactions of 2-substituted cyclohexenes, which are generally less reactive than those having no substituent at the C2 position, with organotin reagents (Migita-Kosugi-Stille coupling) or with Grigard reagents (Kumada-Tamao-Corriu coupling) using a NHC as a ligand was investigated. It was found that NHCs are effective as ligands for these reactions, giving the corresponding cross-coupling products in good yields.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	© 2008 Georg Thieme Verlag KG.
PISSN	0039-7881
EISSN	1437-210X
NCID	AA00855740
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1055/s-2008-1067222