Synthesis of Styrene Carbonate from Carbon Dioxide and Styrene Oxide with Various Zinc Halide-Based Ionic Liquids

Fujita, Shin-ichiro; Nishiura, Masahiro; Arai, Masahiko

Catalysis Letters, 2010, 135(3-4), 263-268

Permalink : https://hdl.handle.net/2115/49860

このアイテムのアクセス数:1,211件（2026-03-14 10:19 集計）

閲覧可能ファイル 

ファイル フォーマット サイズ 閲覧回数 説明
CL135-3-4_263-268 pdf 208 KB 2,757

論文情報

ファイル出力 EndNote Basic出力 Mendeley出力

アクセス権
open access
URI
https://hdl.handle.net/2115/49860
タイトル
Synthesis of Styrene Carbonate from Carbon Dioxide and Styrene Oxide with Various Zinc Halide-Based Ionic Liquids
著者
Fujita, Shin-ichiro ; Nishiura, Masahiro ; Arai, Masahiko
e-Rad_Researcher
80156869
著者名
Fujita, Shin-ichiro
著者名
Nishiura, Masahiro
e-Rad_Researcher
60125490
著者名
Arai, Masahiko
言語
英語
キーワード
Styrene carbonate
Styrene oxide
Carbon dioxide
Binary catalyst
Cycloaddition
発行日
2010-04
出版者
Springer Netherlands
収録物名
Catalysis Letters
巻(号)
135(3-4)
ページ
263-268
抄録
Various zinc halide-based ionic liquids were prepared from zinc halides and onium halides as catalysts for the synthesis of styrene carbonate (SC) from styrene oxide and carbon dioxide. The effects of the ionic liquid catalyst composition (types of onium cation and halide, onium cation/zinc ratio) and CO2 pressure on the reaction were investigated. The effectiveness of the onium cation as the active catalyst component was in the order of tetrabutylammonium > 1-butylpyridinium > 1-butyl-3-methylimidazolium ≫ choline. The type of halide atom originating from the zinc salt affected the catalytic activity of the ionic liquid more significantly than that of the one originating from the onium salt. The onium cation/zinc ratio also affected the SC yield, but its manner was different depending on the type of onium cation. Influence of CO2 pressure was not significant.
資源タイプ
学術雑誌論文
出版タイプ
Accepted Manuscript
権利情報
The final publication is available at www.springerlink.com
PISSN
1011-372X
EISSN
1572-879X
関連情報 (isVersionOf)
出版社版DOI
https://doi.org/10.1007/s10562-010-0286-3