Utilization of Acidic α-Amino Acids as Acyl Donors: An Effective Stereo-Controllable Synthesis of Aryl-Keto α-Amino Acids and Their Derivatives

Wang, Lei; Murai, Yuta; Yoshida, Takuma et al.

Molecules, 2014, 19(5), 6349-6367

Permalink : https://hdl.handle.net/2115/55774

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アクセス権
open access
URI
https://hdl.handle.net/2115/55774
タイトル
Utilization of Acidic α-Amino Acids as Acyl Donors: An Effective Stereo-Controllable Synthesis of Aryl-Keto α-Amino Acids and Their Derivatives
著者
Wang, Lei ; Murai, Yuta ; Yoshida, Takuma ; Okamoto, Masashi ; Tachrim, Zetryana ; Hashidoko, Yasuyuki ; Hashimoto, Makoto
著者名
Wang, Lei
著者名
Murai, Yuta
著者名
Yoshida, Takuma
著者名
Okamoto, Masashi
著者名
Tachrim, Zetryana
e-Rad_Researcher
40281795
著者名
Hashidoko, Yasuyuki
e-Rad_Researcher
90292094
著者名
Hashimoto, Makoto
言語
英語
キーワード
aryl-keto α-amino acid
Friedel-Crafts acylation
Lewis acid
triflic acid
発行日
2014-05
出版者
MDPI
収録物名
Molecules
巻(号)
19(5)
ページ
6349-6367
抄録
Aryl-keto-containing α-amino acids are of great importance in organic chemistry and biochemistry. They are valuable intermediates for the construction of hydroxyl α-amino acids, nonproteinogenic α-amino acids, as well as other biofunctional components. Friedel-Crafts acylation is an effective method to prepare aryl-keto derivatives. In this review, we summarize the preparation of aryl-keto containing α-amino acids by Friedel-Crafts acylation using acidic α-amino acids as acyl-donors and Lewis acids or Brönsted acids as catalysts.
資源タイプ
学術雑誌論文
出版タイプ
Version of Record
権利情報
Creative Commons Attribution 3.0 Unported
PISSN
1420-3049
関連情報 (isIdenticalTo)
出版社版DOI
https://doi.org/10.3390/molecules19056349