Transition metal-catalyzed borylation of alkanes and arenes via C-H activation

Ishiyama, Tatsuo; Miyaura, Norio

Journal of Organometallic Chemistry, 2003, 680(1-2), 3-11

Permalink : https://hdl.handle.net/2115/56230

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アクセス権	open access
URI	https://hdl.handle.net/2115/56230
タイトル	Transition metal-catalyzed borylation of alkanes and arenes via C-H activation
著者	e-Rad_Researcher 00232348 著者名 Ishiyama, Tatsuo
著者	e-Rad_Researcher 10002049 著者名 Miyaura, Norio
言語	英語
キーワード	Transition metal complexes
	Bis(pinacolato)diboron
	Pinacolborane
	Hydrocarbon
	Organoboron compound
	C -H borylation
発行日	2003-08-29
出版者	Elsevier
収録物名	Journal of Organometallic Chemistry
巻(号)	680(1-2)
ページ	3-11
抄録	Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by several groups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety of organoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed C -H borylation of alkanes, arenes and benzylic positions of alkylarenes by bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via C -H activation are summarized.
資源タイプ	学術雑誌論文
出版タイプ	Submitted Manuscript Under Review
PISSN	0022-328X
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1016/S0022-328X(03)00176-1