Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel

Shen, Xiande; Kitajyo, Yoshikazu; Duan, Qian et al.

Polymer Bulletin, 2006, 56(2-3), 137-143

Permalink : https://hdl.handle.net/2115/5737

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アクセス権
open access
URI
https://hdl.handle.net/2115/5737
タイトル
Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel
著者
Shen, Xiande ; Kitajyo, Yoshikazu ; Duan, Qian ; Narumi, Atsushi ; Kaga, Harumi ; Kaneko, Noriaki ; Satoh, Toshifumi ; Kakuchi, Toyoji
著者名
Shen, Xiande
著者名
Kitajyo, Yoshikazu
著者名
Duan, Qian
著者名
Narumi, Atsushi
著者名
Kaga, Harumi
著者名
Kaneko, Noriaki
e-Rad_Researcher
80291235
著者名
Satoh, Toshifumi
e-Rad_Researcher
80113538
著者名
Kakuchi, Toyoji
覚知, 豊次
言語
英語
発行日
2006
出版者
Springer Berlin / Heidelberg
収録物名
Polymer Bulletin
巻(号)
56(2-3)
ページ
137-143
抄録
The reaction of the carboxymethyl cellulose sodium salt (Na-CMC) (degrees of substitution (DS) = 1.2) with N-hydroxysuccinimide (Su-OH) in the presence of 1-hydroxybenzotriazole and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) was carried out in water to obtain the Su-OH ester of carboxymethyl cellulose, Su-CMC, with the DS values of 0.19 – 1.04. N-Allylcarbamoylmethyl cellulose (Allyl-CMC), which was prepared from the reaction of Su-CMC with an excess amount of allylamine, was crosslinked by UV-irradiation. In addition, the photocrosslinked Allyl-CMC film was swollen with water to form a hydrogel having a relatively high water-swelling property, e.g., the degree of swelling (ds) was ca. 360% for Allyl-CMC with the DS of 0.93.
資源タイプ
学術雑誌論文
出版タイプ
Accepted Manuscript
権利情報
The original publication is available at www.springerlink.com
PISSN
0887-624X
関連情報 (isVersionOf)
出版社版DOI
https://doi.org/10.1007/s00289-005-0482-2