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論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/59750
タイトル	Fluorescent poly(boron enaminoketonate)s : synthesis via the direct modification of polyisoxazoles obtained from the click polymerization of a homoditopic nitrile N-oxide and diynes
著者	Matsumura, Tohru ; Koyama, Yasuhito ; Uchida, Satoshi ; Yonekawa, Morio ; Yui, Tatsuto ; Ishitani, Osamu ; Takata, Toshikazu
著者名 Matsumura, Tohru
e-Rad_Researcher 10456262 著者名 Koyama, Yasuhito
著者名 Uchida, Satoshi
著者名 Yonekawa, Morio
著者名 Yui, Tatsuto
e-Rad_Researcher 50272282 著者名 Ishitani, Osamu
e-Rad_Researcher 40179445 著者名 Takata, Toshikazu
言語	英語
キーワード	click polymerization
	fluorescence
	homoditopic nitrile N-oxide
	poly(boron enaminoketonate)
	polyisoxazole
発行日	2014-09
出版者	Society of Polymer Science, Japan
	高分子学会
収録物名	Polymer journal
巻(号)	46(9)
ページ	609-616
抄録	Fluorescent poly(boron enaminoketonate)s (PBEKs) were synthesized via the polycycloaddition of a homoditopic nitrile N-oxide to diynes followed by other polymer reactions. Click polycycloaddition of the nitrile N-oxide to various diynes effectively produced polyisoxazoles in high yields. The polyisoxazoles were transformed into the corresponding fluorescent PBEKs by forming the poly(beta-aminoenone) intermediates and reacting these intermediates with (C6F5)(2)BF center dot OEt2. The solution and solid-state optical properties of the PBEKs were evaluated by ultraviolet-visible (UV-vis) and fluorescence spectroscopy.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
PISSN	0032-3896
EISSN	1349-0540
NCID	AA00777013
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1038/pj.2014.31

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