An Investigation of Ni2P Single Crystal Surfaces : Structure, Electronic State and Reactivity

Yuan, Qiuyi; Ariga, Hiroko; Asakura, Kiyotaka

Topics in catalysis, 2015, 58(4-6), 194-200

Permalink : https://hdl.handle.net/2115/61040

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アクセス権
open access
URI
https://hdl.handle.net/2115/61040
タイトル
An Investigation of Ni2P Single Crystal Surfaces : Structure, Electronic State and Reactivity
著者
Yuan, Qiuyi ; Ariga, Hiroko ; Asakura, Kiyotaka
著者名
Yuan, Qiuyi
e-Rad_Researcher
90570911
著者名
Ariga, Hiroko
e-Rad_Researcher
60175164
著者名
Asakura, Kiyotaka
言語
英語
キーワード
Single crystal surfaces
Nickel phosphide
Electronic structure
Surface structure
Scanning tunneling microscopy
Density functional theory
LEED IV
発行日
2015-04
出版者
Springer
収録物名
Topics in catalysis
巻(号)
58(4-6)
ページ
194-200
抄録
Ni2P has demonstrated high catalytic activity for hydrodesulfurization and has recently been employed as a catalyst in a variety of other reactions. We have thoroughly reviewed the literature concerning Ni2P single crystal surfaces, with the aim of determining the relationship between surface structure and catalytic properties. Published results to date indicate that Ni2P single crystal surfaces exhibit reconstructed structures, and so the bulk terminated structure may not be stable. We have also reviewed the surface structures and electronic states of (1 x 1) and reconstructed Ni2P(0001) and (1010). Based on these reviews, this paper presents general rules regarding stabilization of the Ni2P surface structure and discusses the role of phosphorus in the single crystal surfaces.
資源タイプ
学術雑誌論文
出版タイプ
Accepted Manuscript
権利情報
The final publication is available at link.springer.com
PISSN
1022-5528
関連情報 (isVersionOf)
出版社版DOI
https://doi.org/10.1007/s11244-015-0360-6