The relationship between magneto-optical properties and molecular chirality

Wada, Satoshi; Kitagawa, Yuichi; Nakanishi, Takayuki; Fushimi, Koji; Morisaki, Yasuhiro; Fujita, Koji; Konishi, Katsuaki; Tanaka, Katsuhisa; Chujo, Yoshiki; Hasegawa, Yasuchika

The relationship between magneto-optical properties and molecular chirality

Wada, Satoshi; Kitagawa, Yuichi; Nakanishi, Takayuki et al.

NPG Asia materials, 2016, 8, e251

Permalink : https://hdl.handle.net/2115/61898

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アクセス権	open access
URI	https://hdl.handle.net/2115/61898
タイトル	The relationship between magneto-optical properties and molecular chirality
著者	Wada, Satoshi ; Kitagawa, Yuichi ; Nakanishi, Takayuki ; Fushimi, Koji ; Morisaki, Yasuhiro ; Fujita, Koji ; Konishi, Katsuaki ; Tanaka, Katsuhisa ; Chujo, Yoshiki ; Hasegawa, Yasuchika
著者名 Wada, Satoshi
著者名 Kitagawa, Yuichi
e-Rad_Researcher 30609855 著者名 Nakanishi, Takayuki
e-Rad_Researcher 20271645 著者名 Fushimi, Koji
著者名 Morisaki, Yasuhiro
e-Rad_Researcher 80303593 著者名 Fujita, Koji
e-Rad_Researcher 80234798 著者名 Konishi, Katsuaki
著者名 Tanaka, Katsuhisa
著者名 Chujo, Yoshiki
e-Rad_Researcher 80324797 著者名 Hasegawa, Yasuchika
言語	英語
キーワード	circularly-polarized luminescence
	lanthanide complexes
	chiroptical properties
	optical-activity
	energy-transfer
	enantiopure
	ligands
	europium
	dichroism
	clusters
発行日	2016-03
出版者	Nature Publishing Group
収録物名	NPG Asia materials
巻(号)	8
ページ	e251
抄録	The chiral nonanuclear Tb(III) clusters [Tb-9(sal-(R)-Bt)(16)(mu-OH)(10)]+[NO3]-(Tb-(R)-Bt: sal-(R)-Bt=(R)-2-butyl salicylate) and [Tb9 (sal-(S)-Bt)(16)(mu-OH)(10)](+)[NO3](-)(Tb-(S)-Bt: sal-(S)-Bt=(S)-2-butyl salicylate) were found to exhibit a unique magneto-optical property: the Faraday effect. The clusters were composed of 9 Tb(III) ions bridged by 10 mu-OHs and 16 chiral salicylic acid esters. The Faraday rotation angle of Tb-(R)-Bt was greater than that of Tb-(S)-Bt, indicating that the Faraday effect was affected by the chirality of the Tb(III) clusters. The chiroptical properties of the Tb(III) clusters were estimated using circular dichroism and circularly polarized luminescence. In this study, a new finding concerning chiral magneto-optical properties was investigated.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
権利情報	Creative Commons Attribution 4.0 International
PISSN	1884-4049
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1038/am.2016.17