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HUSCAP-TCR-Ohkuma-2016	pdf	5.37 MB	1,911

論文情報

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アクセス権	open access
URI	https://hdl.handle.net/2115/67735
タイトル	Advancement in Catalytic Asymmetric Hydrogenation of Ketones and Imines, and Development of Asymmetric Isomerization of Allylic Alcohols
著者	e-Rad_Researcher 50201968 著者名 Ohkuma, Takeshi
	著者名 Arai, Noriyoshi
言語	英語
キーワード	asymmetric catalysis
	hydrogenation
	iridium
	isomerization
	ruthenium
発行日	2016-12
出版者	Wiley-Blackwell
収録物名	Chemical record
巻(号)	16(6)
ページ	2801-2819
抄録	Catalytic asymmetric hydrogenation of ketones through the "metal-ligand cooperative mechanism" has been improved in terms of the efficiency, stereoselectivity, and scope of substrates by varying the arrangement of the catalyst structure and reaction conditions. Imino compounds are also smoothly converted to the optically active amines with appropriate catalysts. This type of catalyst exhibits excellent performance on the asymmetric isomerization of primary allylic alcohols into the optically active aldehydes. This personal account describes recent progress on these topics.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	This is the peer reviewed version of the following article: The Chemical Record. 16(6), Dec 2016, pp.2797–2815, which has been published in final form at http://dx.doi.org/10.1002/tcr.201600101. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
PISSN	1527-8999
関連情報	PMID 27555568
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1002/tcr.201600101

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