Optimization of Al2O3 and Li3BO3 Content as Sintering Additives of Li7-xLa2.95Ca0.05ZrTaO12 at Low Temperature

Rosero-Navarro, Nataly Carolina; Miura, Akira; Higuchi, Mikio; Tadanaga, Kiyoharu

Optimization of Al2O3 and Li3BO3 Content as Sintering Additives of Li7-xLa2.95Ca0.05ZrTaO12 at Low Temperature

Rosero-Navarro, Nataly Carolina; Miura, Akira; Higuchi, Mikio et al.

Journal of electronic materials, 2017, 46(1), 497-501

Permalink : https://hdl.handle.net/2115/68021

このアイテムのアクセス数:754件（2026-10-23 12:37 集計）

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アクセス権	open access
URI	https://hdl.handle.net/2115/68021
タイトル	Optimization of Al2O3 and Li3BO3 Content as Sintering Additives of Li7-xLa2.95Ca0.05ZrTaO12 at Low Temperature
著者	Rosero-Navarro, Nataly Carolina ; Miura, Akira ; Higuchi, Mikio ; Tadanaga, Kiyoharu
著者名 Rosero-Navarro, Nataly Carolina
著者名 Miura, Akira
著者名 Higuchi, Mikio
e-Rad_Researcher 90244657 著者名 Tadanaga, Kiyoharu
言語	英語
キーワード	Ca-Ta doped LLZ
	sintering additives
	Al2O3
	Li3BO3
	Li ion conductivity
発行日	2017-01
出版者	Springer
収録物名	Journal of electronic materials
巻(号)	46(1)
ページ	497-501
抄録	Simultaneous effect of Al2O3 and Li3BO3 additions on sintering behavior and Li-ion conductivity of Li7-xLa2.95Ca0.05ZrTaO12 (LLCZT) garnet electrolyte sintered at 900 degrees C (10 h) is evaluated. The crystal phase and microstructure of the different composites were evaluated by x-ray diffraction and scanning electron microscopy (SEM), respectively. Electrical properties of the composites with high relative densities (95%) were examined by impedance spectroscopy. The cubic phase was formed for LLCZT sintered with 0-0.21 mol of Al2O3 and 0.70 mol-0.80 mol of Li3BO3. The excess of Al2O3 (0.22 mol) led to the formation of secondary phases. SEM observation revealed the good interconnection between LLCZT grains and the distribution of the glassy phase formed by Li3BO3 and Al2O3. Effective combination of 0.21 mol of Al2O3 and 0.80 mol of Li3BO3 produced denser material with high relative density of 95% and high Li-ion conduction of 1 x 10(-4) S/cm at 32 degrees C.
資源タイプ	学術雑誌論文
出版タイプ	Accepted Manuscript
権利情報	The final publication is available at Springer via http://dx.doi.org/10.1007/s11664-016-4924-4
PISSN	0361-5235
関連情報 (isVersionOf)	出版社版DOI https://doi.org/10.1007/s11664-016-4924-4