Generation of Radical Species from Cyclohexane-1,2-dione and the Reaction with Olefins : Preparation of 4,5-Dihydro-7(6H)-benzofuranone Derivatives

Miura, Masanori; Arai, Noriyoshi; Narasaka, Koichi

Bulletin of the Chemical Society of Japan, 1998, 71(6), 1437-1441

Permalink : https://hdl.handle.net/2115/70768

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アクセス権	open access
URI	https://hdl.handle.net/2115/70768
タイトル	Generation of Radical Species from Cyclohexane-1,2-dione and the Reaction with Olefins : Preparation of 4,5-Dihydro-7(6H)-benzofuranone Derivatives
著者	Miura, Masanori ; Arai, Noriyoshi ; Narasaka, Koichi
著者名 Miura, Masanori
e-Rad_Researcher 80282721 著者名 Arai, Noriyoshi
著者名 Narasaka, Koichi
言語	英語
発行日	1998
出版者	Chemical Society of Japan
収録物名	Bulletin of the Chemical Society of Japan
巻(号)	71(6)
ページ	1437-1441
抄録	Oxidation of cyclohexane-1,2-dione with ammonium hexanitratocerate(IV) (CAN) generates 2,3-dioxocyclohexyl radical, which reacts with electron-rich olefins to afford the corresponding addition products. The adducts thus generated are converted to 4,5-dihydro-7(6H)-benzofuranone by acid treatment. In addition to cyclohexane-1,2-dione, radical species are also generated from cyclopentane-1,2-dione and cycloheptane-1,2-dione.
資源タイプ	学術雑誌論文
出版タイプ	Version of Record
PISSN	0009-2673
EISSN	1348-0634
NCID	AA00580132
関連情報 (isIdenticalTo)	出版社版DOI https://doi.org/10.1246/bcsj.71.1437